128414-17-5Relevant articles and documents
New methodology for the synthesis of unsaturated 8-, 9- and 10-membered lactams
Evans, P. Andrew,Holmes, Andrew B.,McGeary, Ross P.,Nadin, Alan,Russell, Keith,O'Hanlon, Peter J.,Pearson, Neil D.
, p. 123 - 138 (2007/10/03)
Unsaturated 8-, 9- and 10-membered medium ring lactams 1 (n = 1, 2, 3) have been prepared in good yield by the Claisen rearrangement of the vinyl-substituted precursors 3 in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU).
Stereoselective Synthesis of 3-Amino 1,2-Diols via Intermolecular Pinacol Cross-Coupling of α-Aldehydes with Aliphatic Aldehydes. Short Asymmetric Syntheses of Two 2,3,6-Trideoxy-3-amino Sugars
Konradi, Andrei W.,Pedersen, Steven F.
, p. 4506 - 4508 (2007/10/02)
syn,syn-3-Amino 1,2-diols are prepared via a pinacol cross coupling reaction between N-Cbz- or N-Boc-α-amino aldehydes and aliphatic aldehydes.Application of this methodology to the synthesis of two amino sugars starting from N-Cbz-L-aspartic acid are described.