1284221-15-3Relevant academic research and scientific papers
Regio- and stereoselective multicomponent coupling reaction of alkynes and dimethylzinc involving allylnickelacycles
Mori, Takamichi,Nakamura, Toshiyuki,Onodera, Gen,Kimura, Masanari
, p. 2333 - 2339 (2012)
Nickel catalyzes the multicomponent coupling reaction of vinyl epoxides, alkynes, and dimethylzinc to provide hepta-2,5-dienyl alcohols as a mixture of E- and Z-isomers in high yields. Vinylcyclopropane participates in a similar multicomponent coupling reaction to afford dimethyl α-(hepta-2,5-dienyl) malonates with excellent E-stereoselectivity. Georg Thieme Verlag Stuttgart · New York.
Stereoselective coupling reaction of dimethylzinc and alkyne toward nickelacycles
Mori, Takamichi,Nakamura, Toshiyuki,Kimura, Masanari
scheme or table, p. 2266 - 2269 (2011/06/23)
Chemical equations presented. Ni catalyst promotes the three-component coupling reaction of vinyloxacyclopropane, alkyne, and dimethylzinc to provide 2,5-heptadienyl alcohol in high yields. Vinylcyclopropane also participates in a similar three-component
