128429-58-3Relevant academic research and scientific papers
Synthesis of new types of N,N-disubstituted aminomethylspirophosphoranes
Prishchenko, Andrey A.,Livantsov, Mikhail V.,Novikova, Olga P.,Livantsova, Ludmila I.,Petrosyan, Valery S.
, p. 515 - 520 (2010)
Aminomethylation of several hydrospirophosphoranes and their derivatives, using chloro-, alkoxy-, and amino-substituted methylamines of various structures, is proposed as the convenient method for the synthesis of new N,N-disubstituted aminomethylspiropho
NEW TYPES OF AMINOMETHYL ORGANOPHOSPHORUS COMPOUNDS
Prishchenko, A.A.,Livantsov, M.V.,Petrosyan, V.S.
, p. 1181 - 1193 (2007/10/02)
We studied aminomethylation of various PH acids their derivatives containing highly reactive PH, PSi, POSi and PC(O) fragments: tris(trimethylsilyl)phosphine, trimethylsilyl esters of phosphorus(III) acids, pivaloylphosphonite, and hydrospirophosphoranes.Chloro-, alkoxy- or dialkylaminomethylamines, dialkylformamide acetals, azomethines, and enamines were used as aminomethylating reagents.Convenient methods for synthesizing previously unknown or difficult-to-obtain organic compounds of two-, three-, four, and five-coordinate phosphorus containing a P-C-N fragment were proposed.
