1284293-97-5Relevant academic research and scientific papers
Palladium-catalyzed carbocyclization of alkynyl ketones proceeding through a carbopalladation pathway
Chernyak, Natalia,Gorelsky, Serge I.,Gevorgyan, Vladimir
supporting information; experimental part, p. 2342 - 2345 (2011/04/18)
Dig this: 5-exo-dig carbocyclization of 1 into 2 features intramolecular carbopalladation of alkyne with Pd enolate (see scheme). DFT calculations show that the key Pd enolate forms by deprotonation assisted byb PdII acetate. Subsequent intramo
