128434-32-2

Upstream product

• 1192-78-5 (1R*,2R*,3S*)-2,3-epoxycyclohexanol 
• 7103-09-5 4-but-1-enylmagnesium bromide 

Downstream Products

• 128434-48-0 (3aS,5aR,6R,9aR)-6-Benzyloxy-3-phenylsulfanyl-1,3a,4,5,5a,6,7,8,9,9a-decahydro-pyrrolo[1,2-a]quinoline 
• 128434-48-0 (3aR,5aR,6R,9aR)-6-Benzyloxy-3-phenylsulfanyl-1,3a,4,5,5a,6,7,8,9,9a-decahydro-pyrrolo[1,2-a]quinoline 
• 128434-50-4 (5aS,6S,9aS)-6-Benzyloxy-3-phenylsulfanyl-4,5,5a,6,7,8,9,9a-octahydro-pyrrolo[1,2-a]quinoline 
• 128434-56-0 C₂₃H₂₉NO₂S 
• 128434-54-8 C₂₃H₃₁NO₂S 
• 128434-49-1 (5aR,6R,9aR)-6-Benzyloxy-3-vinyl-4,5,5a,6,7,8,9,9a-octahydro-[1,2,3]triazolo[1,5-a]quinoline 
• 128434-34-4 Methanesulfonic acid (1R,2R,3S)-3-benzyloxy-2-but-3-enyl-cyclohexyl ester 
• 128434-36-6 Methanesulfonic acid (1S,2S,3R)-2-but-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexyl ester 
• 128434-35-5 (1S,2R,3R)-2-But-3-enyl-3-(tert-butyl-dimethyl-silanyloxy)-cyclohexanol 
• 128434-33-3 (1R,2S,3S)-3-Benzyloxy-2-but-3-enyl-cyclohexanol 

Relevant academic research and scientific papers

Assembly of the gephyrotoxin ring system via a [4+1] approach to 3-pyrrolines

Heating azidodienes 19 at 70°C produced the tricyclic 3-pyrrolines 20 and 21 in one operation. The diastereoselectivity of this process was examined, and found to be controlled by the conformation of the cyclization precursor. Compound 20d incorporates the basic features of gephyrotoxin 3.