128434-64-0Relevant academic research and scientific papers
Dephosphorylation of Cyano Diethyl Phosphates by Reduction with Lithium-Liquid Ammonia: An Efficient Method for Conversion of Carbonyl Compounds into Nitriles
Yoneda, Ryuji,Osaki, Takahiro,Harusawa, Shinya,Kurihara, Takushi
, p. 607 - 610 (2007/10/02)
Cyano diethyl phosphate derivatives of aromatic carbonyl compounds and α,β-unsaturated ketones were successively dephosphorylated by reduction with lithium in liquid ammonia followed by treatment with isoprene or alkyl halides to give β,γ-unsaturated nitriles or α-alkyl-β,γ-unsaturated nitriles in moderate to good yields.
