128443-38-9Relevant articles and documents
Oxygen transfer reactions from an oxaziridinium tetrafluoroborate salt to olefins
Lusinchi, Xavier,Hanquet, Gilles
, p. 13727 - 13738 (2007/10/03)
Oxaziridinium 5 efficiently epoxidises olefins. It reacts as an electrophilic reagent and does not transfer its oxygen to deactivated double-bonds or carbonyl functions. Epoxidation of cyclic allylic acetates shows a remarkable diastereoselectivity leading to the syn isomer. We propose that the epoxidation reaction proceeds through a one-step process.