128444-40-6Relevant academic research and scientific papers
The first example of asymmetric induction in an anionic amino-Cope rearrangement
Allin, Steven M.,Button, Martin A. C.
, p. 3345 - 3348 (1998)
The anionic amino-Cope rearrangement of suitably functionalized acyclic 3-amino-1,5-diene substrates has been achieved and we report the first example of an asymmetric anionic amino-Cope rearrangement to yield an enantiomerically enriched product (75% e.e.). The absolute stereochemistry of the products has been verified and transition state models are proposed to rationalize the stereochemical outcome.
Oxidation of aliphatic α,β-unsaturated aldimines to amides specifically by oxone with AlCl3
Lu, Zhou,Peng, Lijun,Wu, Wentao,Wu, Longmin
, p. 2357 - 2366 (2008/09/21)
α,β-Unsaturated aldimines were specifically oxidized to amides with Oxone in the presence of AlCl3 as a Lewis acid in CH2Cl2. No migration of aryl group occurred in the rearrangement reaction. Copyright Taylor & Francis Group, LLC.
Nucleophilic addition to tricarbonyliron(0) complexes of 1-aza-1,3-dienes and the production of pyrroles
Danks, Timothy N.,Thomas, Susan E.
, p. 761 - 765 (2007/10/02)
The synthesis of a number of novel tricarbonyl(1-aza-1,3-diene)iron(0) complexes and their reactions with methyl-lithium are described. Addition proceeds under mild conditions and, in general, occurs at a metal carbonyl ligand; this leads via an unprecedented reaction to the production of several novel pyrroles.
