128459-15-4Relevant academic research and scientific papers
Synthesis of trans- and cis-14-Phenylsulfonyl-1,7,9-trioxadispirohexadecane
Brimble, Margaret A.,Rush, Carolyn J.
, p. 497 - 500 (2007/10/02)
The synthesis of the trans- and cis-isomers 1a and 1b of 14-phenylsulfonyl-1,7,9-trioxadispirohexadecane via the addition of an α-sulfonyl carbanion to δ-valerolactone followed by acid-catalysed cyclization is described.Reductive removal of the s
The Chemistry of Bis-spiroacetals: Synthesis of the Novel 1,7,9-Trioxadispirohexadecane Ring System
Brimble, Margaret A.,Rush, Carolyn J.,Williams, Geoffrey M.,Baker, Edward N.
, p. 414 - 416 (2007/10/02)
The synthesis of the novel bis-spiroacetal (1) via the addition of an α-sulphonyl carbanion to δ-valerolactone followed by an acid catalysed cyclization is described.The stereochemistry was determined by X-ray crystallography and 1H NMR spectroscopy.
