128473-01-8

Upstream product

• 1623-08-1 phosphoric acid dibenzyl ester 
• 120703-59-5 O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)trichloroacetimidate 
• 83866-10-8 2,2,2-Trichloro-acetimidic acid (3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester 

Downstream Products

• 174713-19-0 Boc-(αFuc3,4,5Bn3)-L-Thr-OEt 
• 184005-90-1 (2S,3R)-2-Amino-3-((2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-butyric acid ethyl ester 
• 174713-21-4 (2S,3R)-2-((2S,3R)-4-Benzyloxy-2-tert-butoxycarbonylamino-3-hydroxy-butyrylamino)-3-((2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-butyric acid ethyl ester 
• 174713-22-5 (2S,3R)-2-[(2S,3R)-4-Benzyloxy-2-(4-benzyloxycarbonyl-butyrylamino)-3-hydroxy-butyrylamino]-3-((2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-butyric acid ethyl ester 
• 83866-10-8 2,2,2-Trichloro-acetimidic acid (3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester 
• 33639-75-7 2,3,4-tri-O-benzyl-6-deoxy-D-glucopyranose 

Relevant academic research and scientific papers

Glycosyl Imidates, 47. Stereospecific Synthesis of α- and β-L-Fucopyranosyl Phosphates and of GDP-Fucose via Trichloroacetimidate

Reaction of the benzyl- and acetyl-protected α-trichloroacetimidates 1 and 6α with dialkyl and diaryl phosphates in the presence of traces of acid affords stereoselectively the thermodynamically more stable α-L-fucopyranosyl phosphates 2, 7 and 8, respect

SYNTHESIS OF CYTIDINE DIPHOSPHATE-D-QUINOVOSE

The title molecule, cytidine-D-quinovose (CDP-6-deoxy-D-glucose) 1, was synthesized by two different methods from the key intermediate quinovose-1-phosphate 7 which was prepared from glucose.