128503-24-2

Upstream product

• 128503-23-1 (-)-methyl 5-O-benzyl-6-O-t-butyldimethylsilyl-4-deoxy-2,3-O-isopropylidene-D-lyxo-hexonate 
• 147048-92-8 (-)-methyl 5-O-benzyl-4-deoxy-2,3-O-isopropylidene-D-lyxo-hexonate 
• 128503-20-8 (-)-5-O-acetyl-2-O-benzyl-3-deoxy-β-D-arabino-hexofuranurono-6,1-lactone 
• 128503-23-1 (+/-)-methyl 5-O-benzyl-6-O-t-butyldimethylsilyl-4-deoxy-2,3-O-isopropylidene-DL-lyxo-hexonate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 128503-22-0 (+/-)-methyl 5-O-benzyl-4-deoxy-lyxo-DL-hexonate 
• 147048-91-7 (+/-)-methyl 5-O-benzyl-4-deoxy-2,3-O-isopropylidene-DL-lyxo-hexonate 

Downstream Products

• 24707-42-4 4-deoxy-D-mannopyranoside 
• 13241-00-4 (+/-)-methyl 4-deoxy-DL-lyxo-hexopyranoside 

Relevant academic research and scientific papers

TOTAL ASYMMETRIC SYNTHESES OF 3- AND 4-DEOXY-HEXOSES AND DERIVATIVES.

(1S,4S)-7-Oxabicyclohept-5-en-2-one ((-)-5, a "naked sugar") has been converted to (-)-(1R,4S,6S)-6-endo-benzyloxy-2-bromo-7-oxabicyclohept-2-ene ((-)-12) in a highly stereoselective fashion.Double hydroxylation of the C=C double bond of (-)

THE ELECTRON-RELEASING HOMOCONJUGATED CARBONYL GROUP. APPLICATION TO THE TOTAL SYNTHESES OF 3-DEOXY-,4-DEOXY-HEXOSE,LIVIDOSAMINE AND DERIVATIVES

The regioselective electrophilic addition of benzeneselenyl bromide to (-)-(1S,4S)-7-oxabicyclo-hept-5-en-2-one were exploited to develop efficient syntheses of methyl 3-deoxy-α-D-arabino-hexofuranoside and 4-deoxy-D-lyxo-hexopyranose.Similarly, D-