1285256-89-4Relevant academic research and scientific papers
Enantioselective rhodium-catalyzed allylic Ci-H activation for the addition to conjugated dienes
Li, Qian,Yu, Zhi-Xiang
supporting information; experimental part, p. 2144 - 2147 (2011/04/22)
Easy and efficient: By applying the title transformation, two adjacent sp3 stereogenic centers, one of which is a quaternary carbon center, can be easily formed. This asymmetric reaction provides easy and efficient access to multifunctionalized tetrahydropyrrole, tetrahydrofuran, and cyclopentane compounds (see scheme; coe=cyclooctene, DME=1,2-dimethoxyethane, Tf=trifluoromethanesulfonyl).
