1285537-44-1

Basic information

• Product Name: tert-butyl((4-iodocyclohexyl)oxy)dimethylsilane
• CAS NO: 1285537-44-1
• Molecular Weight: 340.32
• Mol File: 1285537-44-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl((4-iodocyclohexyl)oxy)dimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl((4-iodocyclohexyl)oxy)dimethylsilane(1285537-44-1)
• EPA Substance Registry System: tert-butyl((4-iodocyclohexyl)oxy)dimethylsilane(1285537-44-1)

Safety Data

• Hazardous Substances Data: 1285537-44-1(Hazardous Substances Data)

Upstream product

• 67124-67-8 1-(tert-butyldimethylsiloxy)cyclohexane 

Downstream Products

• 1285537-41-8 trans-4-ethynylcyclohexyl 4-methylbenzenesulfonate 
• 1285537-26-9 tert-butyl((trans-4-((4-iodophenyl)ethynyl)cyclohexyl)oxy)dimethylsilane 
• 1285537-37-2 tert-butyl((cis-4-((4-iodophenyl)ethynyl)cyclohexyl)oxy)dimethylsilane 
• 1285537-25-8 4-((trans-4-((tert-butyldimethylsilyl)oxy)cyclohexyl)ethynyl)benzonitrile 
• 1285537-24-7 tert-butyldimethyl((trans-4-((triisopropylsilyl)ethynyl)cyclohexyl)oxy)silane 
• 1285537-23-6 tert-butyl((trans-4-(4-((tert-butyldimethylsilyl)oxy)but-1-yn-1-yl)cyclohexyl)oxy)dimethylsilane 

Relevant articles and documents

Highly diastereoselective C(sp3)i-C(sp) cross-coupling reactions between 1,3- and 1,4-substituted cyclohexylzinc reagents and bromoalkynes through remote stereocontrol

Under the influence: The use of the readily available and inexpensive orthophenantroline derivative neocuproine as a ligand in the generally applicable and highly stereoselective palladium-catalyzed title reaction results in diastereomeric ratios of up to 98:2. The method can be used for the synthesis of building blocks which may be relevant for the synthesis of liquid crystalline mesogens and their chiral dopants (see scheme, dba=trans,trans- dibenzylideneacetone).