1285664-53-0Relevant academic research and scientific papers
2,6-dibenzhydryl- N -(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamine nickel dibromides: Synthesis, characterization, and ethylene polymerization
Liu, Hao,Zhao, Weizhen,Hao, Xiang,Redshaw, Carl,Huang, Wei,Sun, Wen-Hua
, p. 2418 - 2424 (2011/06/21)
A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4- methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) procatalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 107 g of PE (mol of Ni)-1 h -1.
