128594-82-1Relevant academic research and scientific papers
Reaction of Carbon Dioxide with (Porphyrinato)aluminum Thiolates
Arai, Toru,Sato, Yoshihiro,Inoue, Shohei
, p. 551 - 554 (2007/10/02)
Reaction of (tetraphenylprophyrinato)aluminum thiolate ((TPP)AISR) with CO2 under atmospheric pressure at room temperature afforded (TPP)Al alkylthiocarbonate when R is alkyl or benzyl.Aluminum thiolate complex of capped porphyrin failed to undergo the same reaction, suggesting the importance of the sixth coordination site of aluminum metal.
