128613-53-6

Basic information

• Product Name: trifluoroacetylated 6-deoxygalactose anti-O-benzyloxime
• CAS NO: 128613-53-6
• Molecular Weight: 653.332
• Mol File: 128613-53-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trifluoroacetylated 6-deoxygalactose anti-O-benzyloxime(CAS DataBase Reference)
• NIST Chemistry Reference: trifluoroacetylated 6-deoxygalactose anti-O-benzyloxime(128613-53-6)
• EPA Substance Registry System: trifluoroacetylated 6-deoxygalactose anti-O-benzyloxime(128613-53-6)

Safety Data

• Hazardous Substances Data: 128613-53-6(Hazardous Substances Data)

Upstream product

• 3615-37-0 D-Fucose 
• 685-27-8 2,2,2-trifluoro-N-methyl-N-(2,2,2-trifluoroacetyl)acetamide 
• 622-33-3 N-benzyloxyamine 

Relevant articles and documents

Capillary gas-chromatographic analysis of monosaccharides: Improvements and comparisons using trifluoroacetylation and trimethylsilylation of sugar O-benzyl- and O-methyl-oximes

Two new procedures for the gas-chromatographic analysis of monosaccharides are reported. One involves derivatization of the sugars by reaction with O-benzylhydroxylamine followed by trifluoroacetylation with N-methylbis(trifluoroacetamide) and chromatography on a DB-1701 capillary column. This technique probably provides the best resolution achieved to date of the C3-C6 aldoses, as well as of the corresponding alditols. Ketoses can be qualitatively analyzed by this method, but complications interfere with their quantitative analysis. The second procedure also involves initial derivatization as the O-benzyloxime, but is followed by trimethylsilylation with 1-trimethylsilylimidazole, and chromatography on a DB-17 column. This technique is particularly useful for C5 sugars, C6 ketoses, and mixtures of sugars, alditols, and/or lactones. A number of additional, critical, observations on the derivatization and capillary gas-chromatographic analysis of monosaccharides are described.