1286254-55-4Relevant articles and documents
A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids
Liao, Longyan,Jana, Ranjan,Urkalan, Kaveri Balan,Sigman, Matthew S.
supporting information; experimental part, p. 5784 - 5787 (2011/06/10)
A three-component coupling of vinyl triflates and boronic acids to alkenes catalyzed by palladium is reported. Using 1,3-dienes, selective 1,2-alkene difunction-alization is observed, whereas the use of terminal alkenes results in 1,1-alkene difunctionalization. The reaction outcome is attributed to the formation of stabilized, cationic Pd-π-allyl intermediates to regulate β-hydride elimination.