1286320-46-4Relevant academic research and scientific papers
Reaction of red phosphorus with allylbenzene in superbasic system KOH-DMSO
Malysheva, Svetlana F.,Belogorlova, Natal'Ya A.,Gusarova, Nina K.,Artem'Ev, Alexander V.,Albanov, Alexander I.,Trofimov, Boris A.
, p. 1688 - 1693 (2011)
Red phosphorus reacts with allylbenzene in the superbase system KOH-DMSO (130C, 3 h, Ar) to give a mixture of bis(1-methyl-2-phenylethyl)phosphane (1), bis(1-methyl-2-phenylethyl)phosphane oxide (2), and 1-methyl-2- phenylethylphosphinic acid (3). Secondary phosphane oxide 2 and phosphinic acid 3 have been isolated from this mixture in 35% and 32% yield, respectively. Microwave activation of the reaction (200 W, 30 min) affords secondary phosphane 1 as the main product in 48% yield. Copyright Taylor &Francis Group, LLC.
