128653-27-0Relevant academic research and scientific papers
Electrochemical Decomplexation of Phosphine-Pentacarbonyltungsten Complexes: The Phosphole Case
Yakhvarov, Dmitry G.,Budnikova, Yulia H.,Huy, Ngoc Hoa Tran,Ricard, Louis,Mathey, Francois
, p. 1961 - 1964 (2004)
Summary: Electrochemical reduction of phosphole P-W-(CO)5 complexes affords the free phospholes in good yields. This technique allows the decomplexation of a 2-ethoxy-4-keto-4,5-dihydrophosphole, which has been characterized by X-ray crystal structure analysis of its P-sulfide.
Using monovalent phosphorus compounds to form P-C bonds
Ng, Yong Xiang,Mathey, Francois
supporting information, p. 14140 - 14142 (2014/01/06)
User friendly P-C: Electrophilic terminal phosphinidene complexes [RP-W(CO)5] react with Ar-B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P-C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P-H bond that can be used for further transformations. Copyright
