1286749-28-7Relevant academic research and scientific papers
Iodobenzene-catalyzed intramolecular oxidative cyclization reactions of ss-Alkynyl β-Ketoesters
Rodriguez, Arantxa,Moran, Wesley J.
, p. 2220 - 2223 (2011)
Chemical equations presented. Iodobenzene is shown to catalyze the 5-exo-dig cyclization of ss-alkynyl β-ketoesters under oxidative conditions that generate hypervalent iodine species in situ. The cyclopentane products contain adjacent quaternary and tertiary stereocenters which are generated with excellent diastereoselectivity.
