1286763-68-5Relevant academic research and scientific papers
An annulative electrophilic amination approach to 3-aminobenzoheteroles
Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
supporting information; experimental part, p. 617 - 625 (2012/02/16)
A copper-catalyzed annulative amination approach to 3-aminobenzofurans and -indoles from o-alkynylphenols and -anilines has been developed. The Cu-based catalysis is based on an umpolung, electrophilic amination with O-benzoyl hydroxylamines and enables t
Copper-catalyzed direct amination of polyfluoroarenes and azoles with hydroxylamines and its application to the synthesis of 3-aminobenzoheteroles
Matsuda, Naoki,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
experimental part, p. 1792 - 1797 (2012/07/28)
A copper-catalyzed electrophilic, umpolung amination strategy for the direct C-H amination of polyfluoroarenes and 1,3-azoles has been developed. The copper-based amination reaction is robust and can be easily scaled up on a gram scale. Its application to
Copper-catalyzed annulative amination of ortho -alkynylphenols with hydroxylamines: Synthesis of 3-aminobenzofurans by umpolung amination strategy
Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
scheme or table, p. 2395 - 2397 (2011/06/28)
Chemical equations presented. A room temperature copper-catalyzed annulative amination of ortho-alkynylphenols with electrophilic amination reagents, O-acylated hydroxylamines, proceeds efficiently to provide the corresponding 3-aminobenzofurans of biolog
