1286788-83-7Relevant academic research and scientific papers
A microwave-assisted domino rearrangement of propargyl vinyl ethers to multifunctionalized aromatic platforms
Tejedor, David,Mendez-Abt, Gabriela,Cotos, Leandro,Ramirez, Miguel A.,Garcia-Tellado, Fernando
, p. 3318 - 3321 (2011)
H makes a difference! A novel reactivity profile of propargyl vinyl ethers has been developed, which is controlled by the presence of a hydrogen atom at the homopropargylic position (see scheme; EWG=electron-withdrawing group). This strategy was conveniently used to construct multifunctionalized phenolic platforms, including salicylaldehydes and the corresponding ketone derivatives. Copyright
