1287215-94-4Relevant academic research and scientific papers
Neighboring acetal-assisted bronsted-acid-catalyzed Si-H bond activation: Divergent synthesis of functional siloxanes through silylation and hydrolytic oxidation of organosilanes
Chen, Xi-Huai,Deng, Yuan,Jiang, Kezhi,Lai, Guo-Qiao,Ni, Yong,Yang, Ke-Fang,Jiang, Jian-Xiong,Xu, Li-Wen
, p. 1736 - 1742 (2011)
A novel metal-free intramolecular Bronsted-acid-catalyzed domino deprotection-hydrosilylation with hydrosilanes has been developed, and the unexpected Bronsted-acid-catalyzed intermolecular hydrolytic oxidation to functional siloxanes was described for the divergent and facile synthesis of functionalized siloxanes containing aldehyde motifs. We propose that these reactions proceed via neighboring acetal-assisted Si-H bond activation. In addition, a related reaction is expected to open up further opportunities for the development and application of functional organosilicon compounds by organocatalysis. Copyright
