1287228-23-2

Upstream product

• 1287228-22-1 (4S,5S,Z)-4-(benzyloxy)-5-((tert-butoxycarbonyl)amino)-6-hydroxyhex-2-en-1-yl acetate 
• 1287228-21-0 (S)-tert-butyl 4-((S,Z)-4-acetoxy-1-(benzyloxy)but-2-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylate 
• 1287228-20-9 (S)-tert-butyl 4-((S,Z)-1-(benzyloxy)-4-hydroxybut-2-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylate 
• 1287228-19-6 (S)-tert-butyl 4-((S,Z)-1-(benzyloxy)-4-((tert-butyldimethylsilyl)oxy)but-2-en-1-yl)-2,2-dimethyloxazolidine-3-carboxylate 

Downstream Products

• 1287228-26-5 tert-butyl ((3S,4R,5R)-4-(benzyloxy)-5-((E)-tetradec-1-en-1-yl)tetrahydrofuran-3-yl)carbamate 

Relevant academic research and scientific papers

Asymmetric synthesis of Pachastrissamine (Jaspine B) and its diastereomers via η3-allylpalladium intermediates

A short route for the synthesis of Pachastrissamine (Jaspine B), an anhydrosphingosine derivative, and all three of its diastereomers is presented. The route consists of only 9 steps from the commercially available Garner's aldehyde. The furan framework is formed via an η3-allylpalladium intermediate.