128735-98-8Relevant articles and documents
Completely regioselective reversals for an addition reaction of ambident sulphur nucleophiles to Michael acceptors
Kpegba, Kafui,Metznei, Patrick
, p. 1853 - 1856 (2007/10/02)
Reacion of titanium enethiolates with α-unsaturated ketones leads selectively to 3-hydroxy 4-saturated alkanedithioates, arising from a 1,2-carbon-addition, whereas aluminum enethiolates give oxoketene dithioacetals, from exclusove 1,4-sulphur-addition. Reaction of titanium enethiolates with α-unsaturated ketones leads selectively to 3-hydroxy 4-unsaturated alkanedithioates, arising from a 1,2-carbon-addition, whereas aluminium enethiolates give oxoketene dithioacetals, from exclusive 1,4-sulphur-addition. (Chemical Equation Presented).