128752-12-5Relevant academic research and scientific papers
INORGANIC RING SYSTEMS CONTAINING LANTHANIDE ELEMENTS
Recknagel, Anja,Wedler, Michael,Knoesel, Friedrich,Edelmann, Frank T.
, p. 189 - 192 (2007/10/02)
Lanthanide complexes containing four-membered N-C-N-Ln, N-S-N-Ln and N-P-N-Ln rings have been synthesized by treatment of lanthanide halides with bulky anionic chelating ligands.Similar ring systems containing four different elements (N-Si-O-Ln) have been obtained by reacting anhydrous lanthanide trichlorides with LitBu)(NtBu)>.A twelve-membered inorganic ring is formed during the reaction of Cp*2Sm(THF)2 with 2.
