1287777-24-5Relevant articles and documents
Drum-like Metallacages with Size-Dependent Fluorescence: Exploring the Photophysics of Tetraphenylethylene under Locked Conformations
Guo, Zhewen,Li, Guangfeng,Wang, Heng,Zhao, Jun,Liu, Yuhang,Tan, Hongwei,Li, Xiaopeng,Stang, Peter J.,Yan, Xuzhou
, p. 9215 - 9221 (2021)
Materials with aggregation-induced emission (AIE) properties are of growing interest due to their widespread applications. AIEgens, such as tetraphenylethylene units, display varying emission behaviors during their conformational changes. However, the str
Divergent and Stereoselective Synthesis of Tetraarylethylenes from Vinylboronates
Stang, Peter J.,Yao, Yisen,Zhang, Minghao,Zhao, Wanxiang
supporting information, p. 20090 - 20098 (2020/09/02)
The synthesis of a new tetraborylethylene (TBE) is reported, and its application in the preparation of [4+0]-tetraarylethenes (TAEs) is elucidated. TAEs have widespread applications in material science and supramolecular chemistry due to their aggregation-induced emission (AIE) properties. The divergent and stereoselective synthesis of [3+1]-, [2+2]-, and [2+1+1]-TAEs via multiple couplings of vinylboronates with aryl bromides is demonstrated. These couplings feature a broad substrate scope and excellent functional group compatibility due to mild reaction conditions. Facile access to various tetraarylethenes is provided. This strategy represents an important complement to the conventional methods employed for the synthesis of TAEs, and would be a valuable tool for synthesizing TAE-based molecules useful in functional materials, biological imaging and chemical sensing.
Coordination-enhanced luminescence on tetra-phenylethylene-based supramolecular assemblies
Yan, Qian-Qian,Hu, Shao-Jun,Zhang, Guang-Lu,Zhang, Ting,Zhou, Li-Peng,Sun, Qing-Fu
, (2018/02/17)
Materials with aggregation-induced emission (AIE) properties have received increased attention recently due to their potential applications in light-emitting devices, chemo/biosensors and biomedical diagnostics. In general, AIE requires the forced aggrega
Halogen bonded networks from pyridyl-substituted tetraarylethylenes and diiodotetrafluorobenzenes
Pigge, F. Christopher,Kapadia, Pradeep P.,Swenson, Dale C.
, p. 4386 - 4391 (2013/08/26)
Three halogen bonded co-crystals between tetraphenylethylene derivatives with peripheral pyridine groups and 1,4- or 1,2-diiodotetrafluorobenzene have been characterized. Two crystalline networks prepared from 3-pyridyl-substituted tetraphenylethylene exh
Tetrapyridyl tetraphenylethylenes: Supramolecular building blocks with aggregation-induced emission properties
Kapadia, Pradeep P.,Widen, John C.,Magnus, MacKenzie A.,Swenson, Dale C.,Pigge, F. Christopher
experimental part, p. 2519 - 2522 (2011/05/09)
Two tetrapyridyl-substituted tetraphenylethylenes have been prepared via Suzuki coupling between tetrabromo tetraphenylethylene and 3- or 4-pyridine boronic acid. Both compounds exhibit aggregation-induced emission as determined by solid state fluorescenc