128796-45-2

Basic information

• Product Name: Boroxin, tris[4-(trifluoromethyl)phenyl]-
• CAS NO: 128796-45-2
• Molecular Formula: C21H12B3F9O3
• Molecular Weight: 515.743
• Mol File: 128796-45-2.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: Boroxin, tris[4-(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Boroxin, tris[4-(trifluoromethyl)phenyl]-(128796-45-2)
• EPA Substance Registry System: Boroxin, tris[4-(trifluoromethyl)phenyl]-(128796-45-2)

Safety Data

• Hazardous Substances Data: 128796-45-2(Hazardous Substances Data)

Upstream product

• 150-46-9 triethyl borate 
• 402-43-7 p-trifluoromethylphenyl bromide 
• 128796-39-4 4-trifluoromethylphenylboronic acid 

Downstream Products

• 98-08-8 α,α,α-trifluorotoluene 
• 402-44-8 4-Fluorobenzotrifluoride 
• 113845-69-5 4-(4-trifluoromethylphenyl)morpholine 
• 1424035-30-2 (S)-2-(1-(4-(trifluoromethyl)phenyl)ethyl)naphthalene 
• 1424035-46-0 (R)-2-(1-(4-(trifluoromethyl)phenyl)propyl)naphthalene 
• 1426442-26-3 (R)-2-(phenyl(4-(trifluoromethyl)phenyl)methyl)naphthalene 
• 1424035-53-9 (S)-2-(phenyl(4-(trifluoromethyl)phenyl)methyl)naphthalene 
• 1404231-85-1 N-4-(N-Boc-4-(4-(trifluoromethyl)phenyl)piperidinyl)isopropanesulfinylamine 
• 1352650-36-2 3-[4-(trifluoromethyl)phenyl]fluoranthene 
• 1338045-73-0 C₂₁H₂₃F₃O₅ 
• 73773-15-6 (S)-p-tolyl(p-(trifluoromethyl)phenyl)methanol 
• 460743-71-9 2-(4-(trifluoro-methyl)phenyl)naphthalene 
• 1313872-39-7 C₁₄H₁₈F₃NO₂S 
• 1313506-49-8 4-[4-(trifluoromethyl)phenyl]pyrene 

Relevant articles and documents

Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes

The reaction of 1-(trifluoromethyl)alkenes (CF3CH=CHR) with arylboroxines (ArBO)3 in the presence of a chiral diene-rhodium catalyst gave high yields of chiral 1,1-difluoroalkenes (CF2=CHC?HArR) with high enantioselectivity (≥95% ee). The reaction is assumed to proceed through β-fluoride elimination of a β,β,β-trifluoroalkylrhodium intermediate that is generated by arylrhodation of the 1-(trifluoromethyl)alkene.

Copper-Catalyzed Asymmetric Arylation of N-Heteroaryl Aldimines: Elementary Step of a 1,4-Insertion

Copper complexes of monodentate phosphoramidites efficiently promote asymmetric arylation of N-azaaryl aldimines with arylboroxines. DFT calculations and experiments support an elementary step of 1,4-insertion in the reaction pathway, a step in which an aryl-copper species adds directly across four atoms of C=N?C=N in the N-azaaryl aldimines.

Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acids

By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon-carbon homologation of aryl and vinyl boroxines using TMSCHN2, giving access to TMS-pinacol boronic ester products, was developed.