128807-21-6Relevant academic research and scientific papers
Bottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons
Feng, Xinliang,Liu, Junzhi
, p. 211 - 222 (2020/02/18)
Bottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands. 1 Introduction 2 Nitrogen-Doped PAHs Based on Dibenzo-9a-azaphenalene (DBAP) 3 Cationic Nitrogen-Doped Helical PAHs 4 Nitrogen-Boron-Nitrogen-Doped PAHs 5 Conclusion and Outlook.
6,12,18-triaryl-5,11,17-benzotriquinoline derivative and synthetic method thereof
-
Paragraph 0042; 0043; 0044, (2017/08/28)
The invention discloses a 6,12,18-triaryl-5,11,17-benzotriquinoline derivative and a synthetic method thereof. The 6,12,18-triaryl-5,11,17-benzotriquinoline derivative, shown as a structural formula below, has a large planar rigid aromatic nucleus, has a
Recognition of G-quadruplex DNA by triangular star-shaped compounds: With or without side chains?
Bertrand, Helene,Granzhan, Anton,Monchaud, David,Saettel, Nicolas,Guillot, Regis,Clifford, Sarah,Guedin, Aurore,Mergny, Jean-Louis,Teulade-Fichou, Marie-Paule
supporting information; experimental part, p. 4529 - 4539 (2011/06/24)
We report the synthesis of two new series of triangular aromatic platforms, either with three aminoalkyl side chains (triazatrinaphthylene series, TrisK: six compounds), or without side chains (triazoniatrinaphthylene, TrisQ). The quadruplex-DNA binding b
