128917-42-0Relevant academic research and scientific papers
Novel photoadditions of tertiary amines to the α-position of α,β-unsaturated γ,δ-epoxy nitriles
Ishii, Keitaro,Hakamada, Satoshi,Nagano, Mayumi,Noji, Masahiro,Sugiyama, Shigeo,Kotera, Masashi,Sakamoto, Masanori
, p. 1592 - 1598 (2002)
The photoreactions of α,β-unsaturated γ,δ-epoxy nitriles 1,2,13 and 16 with triethylamine give rise to novel 1:1 α-adducts (e.g.,5) efficiently. After treatment with silica gel, the adducts undergo retro-Michael reaction leading to the corresponding α-alk
