128930-99-4Relevant academic research and scientific papers
KONJUGIERTE ADDITION VON ALKYLDERIVATEN DER SPAETEN UEBERGANGSMETALLE Ag, Pd, Rh, Ru, Co UND Fe AN 2-CYCLOHEXENON
Kauffmann, Thomas,Huelsduenker, Achim,Menges, Detlef,Nienaber, Hubert,Rethmeier, Lutz,et al.
, p. 1553 - 1556 (2007/10/02)
In situ prepared alkyl derivatives of the 4d metals Ag, Rh (Alk = Me, n-Bu), Pd, Ru (Alk = Me) alkylate 2-cyclohexenone (1) exclusively or preferently in β-position to the keto group.The same was observed by applying Me2Fe, Me3FeLi or the hetero-ate complexes Me2(t-BuO)2FeLi2 and Me2(t-BuO)2CoLi2, whereas Me4FeLi2 methylates 1 at the keto group.
