1289377-50-9

Basic information

• Product Name: (2S,3S)-5-(benzyloxy)-3-methoxy-2-methylpentanal
• Synonyms: (2S,3S)-5-(benzyloxy)-3-methoxy-2-methylpentanal
• CAS NO: 1289377-50-9
• Molecular Weight: 236.311
• Mol File: 1289377-50-9.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-5-(benzyloxy)-3-methoxy-2-methylpentanal(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-5-(benzyloxy)-3-methoxy-2-methylpentanal(1289377-50-9)
• EPA Substance Registry System: (2S,3S)-5-(benzyloxy)-3-methoxy-2-methylpentanal(1289377-50-9)

Safety Data

• Hazardous Substances Data: 1289377-50-9(Hazardous Substances Data)

Upstream product

• 1391093-69-8 (2R,3S)-5-(benzyloxy)-3-methoxy-2-methylpentan-1-ol 
• 1391093-66-5 ((2R,3S)-5-(benzyloxy)-3-methoxy-2-methylpentyloxy)(tert-butyl)dimethylsilane 
• 1289377-46-3 C₁₅H₂₂O₂ 
• 909803-71-0 (3S,4R)-1-Benzyloxy-4-methyl-hex-5-en-3-ol 

Downstream Products

• 1289377-52-1 C₂₂H₃₈O₄ 
• 1289377-53-2 C₃₄H₆₆O₄Si₂ 
• 1289377-58-7 C₂₅H₄₂O₄ 
• 1289377-51-0 C₂₂H₃₆O₄ 
• 1391093-59-6 (2S,3R,4S,5S,6S,7S)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-9-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-7-methoxy-3-(methoxymethoxy)-2,4,6-trimethylnonan-1-one 
• 1391093-78-9 (2S,3R,4S,5S,6S,7S)-9-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-7-methoxy-3-(methoxymethoxy)-2,4,6-trimethylnonanal 
• 1391093-79-0 (5S,6S,7S)-7-((2S,3S)-5-(benzyloxy)-3-methoxypentan-2-yl)-6,9,9,10,10-pentamethyl-5-((R)-pent-3-en-2-yl)-2,4,8-trioxa-9-silaundecane 
• 1391093-72-3 (2R,3S,4S,5S)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-7-(benzyloxy)-3-(tert-butyl-dimethylsilyloxy)-5-methoxy-2,4-dimethylheptan-1-one 
• 1391093-75-6 (2R,3S,4S,5S)-7-(benzyloxy)-3-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylheptanal 
• 1391093-61-0 (2R,3S,4R,5S)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-7-(benzyloxy)-3-hydroxy-5-methoxy-2,4-dimethylheptan-1-one 

Relevant articles and documents

Stereoselective synthesis of the common polyketide fragment of hoiamides

Stereoselective synthesis of the polyketide fragment commonly present in hoiamide A, B, and C is described using iterative Crimmins aldol reaction as the key reaction.

Total synthesis of hoiamide C

Chemical equations presented. Hoiamide C was synthesized in 16 steps with an overall yield of 1.8% starting from homoallylic alcohol 18, unambiguously confirming its structure.