128939-14-0

Basic information

• Product Name: [2-Allyl-2-hydroxy-cyclohex-(E)-ylideneamino]-acetic acid methyl ester
• CAS NO: 128939-14-0
• Molecular Weight: 225.288
• Mol File: 128939-14-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-Allyl-2-hydroxy-cyclohex-(E)-ylideneamino]-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [2-Allyl-2-hydroxy-cyclohex-(E)-ylideneamino]-acetic acid methyl ester(128939-14-0)
• EPA Substance Registry System: [2-Allyl-2-hydroxy-cyclohex-(E)-ylideneamino]-acetic acid methyl ester(128939-14-0)

Safety Data

• Hazardous Substances Data: 128939-14-0(Hazardous Substances Data)

Upstream product

• 765-87-7 cyclohexane-1,2-dione 
• 60277-96-5 2-allyl-2-hydroxycyclohexanone 
• 616-34-2 methoxycarbonylmethylamine 

Downstream Products

• 128939-24-2 (1-Allyl-2-oxo-cyclohexylamino)-acetic acid methyl ester 

Relevant articles and documents

THERMAL REARRANGEMENT OF α-HYDROXY IMINES WITH AN α-ALLYL OR AN α-PROPARGYL SUBSTITUENT

In refluxing diglyme, the title α-hydroxy imines 7 and 8 rearrange cleanly to amino ketones 9 and 10 substituted on the carbon α to nitrogen by an allyl or a propargyl group.In the case of α-hydroxy imine 9, the migration of the allyl group occurs with an allylic transposition.