128946-37-2

Upstream product

• 34245-85-7 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranosyl bromide 
• 128946-36-1 methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 31077-89-1 1,3,4,6-tetra-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranose 
• 39110-57-1 methyl 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranoside 
• 39110-58-2 methyl 2-deoxy-2-fluoro-β-D-glucopyranoside 
• 128854-96-6 methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-3-O-(trifluoromethylsulfonyl)-β-D-glucopyranoside 
• 128855-01-6 methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-3-O-(methylsulfonyl)-β-D-glucopyranoside 

Downstream Products

• 128854-98-8 methyl 3-azido-4-O-benzoyl-2,3,6-trideoxy-2-fluoro-β-D-ribo-hex-5-enopyranoside 
• 128854-97-7 methyl 3-azido-4-O-benzoyl-2,3,6-trideoxy-2-fluoro-β-D-allopyranoside 

Relevant academic research and scientific papers

Synthesis of 3-amino-2,3,6-trideoxy-2-fluoro-L-talose and -D-allose [(R)-2-fluoro-L-daunosamine and (R)-2-fluoro-D-ristosamine]

The title compounds were synthesized (as methyl glycosides) starting from 1,3,4,6-tetra-O-acetyl-2-deoxy-2-fluoro-beta-D-glucopyranose. Stereoselective methods of glycosylation gave, via the tri-O-acetylglycopyranosyl bromide, the methyl 2-deoxy-2-fluoro-