128949-39-3Relevant articles and documents
THE KINETIC ANOMERIC EFFECT. ADDITIONS OF NUCLEOPHILES AND OF DIPOLAROPHILES TO N-GLYCOSYLNITRONES AND TO N-PSEUDOGLYCOSYLNITRONES.
Huber, Rolf,Vasella, Andrea
, p. 33 - 58 (2007/10/02)
To prove the hypothesis of the role of a kinetic anomeric effect in the highly diastereoselective additions of nucleophiles and of dipolarophiles to N-glycosylnitrones, we compared these additions to those analogous N-pseudoglycosylnitrones, having a meth