1289642-97-2

Basic information

• Product Name: (R,E)-ethyl 2-[(tert-butylsulfinyl)imino]-2-(3,5-difluorophenyl)acetate
• Synonyms: (R,E)-ethyl 2-[(tert-butylsulfinyl)imino]-2-(3,5-difluorophenyl)acetate
• CAS NO: 1289642-97-2
• Molecular Weight: 317.357
• Mol File: 1289642-97-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R,E)-ethyl 2-[(tert-butylsulfinyl)imino]-2-(3,5-difluorophenyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-ethyl 2-[(tert-butylsulfinyl)imino]-2-(3,5-difluorophenyl)acetate(1289642-97-2)
• EPA Substance Registry System: (R,E)-ethyl 2-[(tert-butylsulfinyl)imino]-2-(3,5-difluorophenyl)acetate(1289642-97-2)

Safety Data

• Hazardous Substances Data: 1289642-97-2(Hazardous Substances Data)

Upstream product

• 208259-57-8 ethyl 2-(3,5-difluorophenyl)-2-oxoacetate 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 

Downstream Products

• 1289643-09-9 (R)-ethyl 2-(3,5-difluorophenyl)-2-[(R)-1,1-dimethylethylsulfinamido]acetate 

Relevant articles and documents

Asymmetric synthesis of α-amino acids by reduction of N-tert-butanesulfinyl ketimine esters

A highly regio- and diastereoselective reduction of various N-tert-butanesulfinyl ketimine esters with L-Selectride resulting in the formation of α-amino acids is reported. This method is quite general and also practical for the preparation of both enantiomers of aryl or aliphatic α-amino acids in high yields.