128995-29-9Relevant academic research and scientific papers
C-glycosidations of a 2-ketohexosyl bromide with electrophilic, radical, and nucleophilic anomeric carbons
Lichtenthaler, Frieder W.,Lergenmueller, Matthias,Schwidetzky, Sabine
, p. 3094 - 3103 (2007/10/03)
The susceptibility of acylated 2-ketohexosyl halides to Chomologation is demonstrated with the easily accessible tri-O-benzoyl-α-D-arabino-hexos-ulosyl bromide 1 as the model compound. C-Glycosidation with an electrophilic anomeric carbon requires prior c
An expedient route to acylated glucosyl halides with a free 2-OH group
Lichtenthaler, Frieder W.,Koehler, Bernd
, p. 77 - 86 (2007/10/02)
The carbonyl group of 3,4,6-tri-O-benzoyl-α-D-arabino-hexosyl-2-ulose bromide (8), readily accessible from the hydroxyglycal ester, can be reduced by cyanoborohydride without affecting the anomeric bromine; exclusive axial attack of the hydride affords th
Acylated 2-oxoglycosyl bromides: Exploration of their reaction potential
Lichtenthaler, Frieder W.,Schwidetzky, Sabine,Nakamura, Katsumi
, p. 71 - 74 (2007/10/02)
Acylated glycos-2-ulosyl bromides give a variety of useful ensuing reactions, preparatively most relevant being their smooth α- and β-selective glycosidation, their reduction to glucosyl bromides with a free 2-OH, and their C-homologation to higher-carbon
