129031-81-8Relevant articles and documents
A facile asymmetric approach to the multicyclic core structure of mangicol A
Ying, Jun,Pu, Lin
, p. 16301 - 16307 (2014)
Chiral propargylic ether-based triene-ynes are synthesized with high enantiomeric purity by employing an asymmetric enyne addition to aldehydes catalyzed by 1,1′-bi-2-naphthol in combination with ZnEt2, Ti(OiPr)4 and dicy-clohexylami
Synthetic and Kinetic Studies of the Intramolecular Diels-Alder Reactions of Cycloalkenylallenylphosphine Oxides
Curtin, Michael L.,Okamura, William H.
, p. 5278 - 5287 (2007/10/02)
Kinetic investigations reveal that diphenylphosphinoyl (diphenylphosphine oxide) substituted cycloalkenylallenes 13b-d undergo intramolecular Diels-Alder (IMDA) cyclizations at room temperature to afford adducts with gem-dialkyl effect accelerations of 4.