129053-36-7Relevant academic research and scientific papers
Phenylthio (and phenylseleno)fluorination of alkenes and alkynes using N-phenylthio (and phenylseleno)phthalimide combined with pyridine*9HF or Et3N*3HF complexes
Saluzzo, Christine,Spina, Anna-Maria La,Picq, Dominique,Alvernhe, Gerard,Anker, Daniel,et al.
, p. 831 - 843 (2007/10/02)
N-Phenylthiophthalimide and N-phenylselenophthalimide combined with pyridine*9HF or Et3N*3HF complexes allow the formal addition of elements of PHSF or PhSeF across the carbon-carbon double or triple bond by a one-pot reaction.Pyridine*9HF, a strongly aci
Fluoroselenenylation of Alkynes
Usuki, Yoshinosuke,Iwaoka, Michio,Tomoda, Shuji
, p. 1507 - 1510 (2007/10/02)
Benzeneselenenyl fluoride equivalent was generated in situ by the reaction of silver(I) fluoride with benzeneselenenyl bromide in dichloromethane under ultrasound irradiation.Treatment of internal alkynes with this reagent afforded 2-fluoro-1-alkenyl phen
Phenylselenofluoration d'alcynes
Saluzzo, Christine,Alvernhe, Gerard,Anker, Daniel,Haufe, Guenter
, p. 2127 - 2130 (2007/10/02)
The electrophilic anti-addition of the elements of benzeneselenenyl fluoride towards carbone-carbone triple bonds is performed by a one-pot reaction of N-phenylselenophthalimide and triethylamine tris-hydrofluoride with disubstituted alkynes ; starting from monosubstituted alkynes, the reaction proceeds further to afford vinylic diselenated compounds after hydrofluoric acid elimination. Some products of mono-addition could be transformed into vinylic or allenic fluorides.
