129083-28-9Relevant academic research and scientific papers
A practical route to (E)-γ-hydroxy-αβ-unsaturated phenyl sulfones
Dominguez, Esteban,Carretero, Juan Carlos
, p. 7197 - 7206 (2007/10/02)
Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1) in the presence of piperidine in acetonitrile gave selectively E-γ-hydroxy-αβ-unsaturated phenyl sulfones (2) in good yields. Reaction from enantiomerically pure sulfoxide 1 gave unsaturated sulfones 2 in moderate optical yields (ee= 10-50%).
Facile synthesis of E-γ-hydroxy-α,β-unsaturated sulfones from aldehydes
Dominguez,Carretero
, p. 2487 - 2490 (2007/10/02)
Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1), in the presence of piperidine in acetonitrile at 0°C, gave selectively E-γ-hydroxy-α,β-unsaturated phenyl sulfones in good yields.
