1291070-05-7

Upstream product

• 132407-50-2 (R)-tert-butyl((3,7-dimethylocta-1,6-dien-3-yl)oxy)dimethylsilane 
• 126-91-0 linalool 
• 1291070-01-3 (1S,4S)-4-((tert-butyldimethylsilyl)oxy)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-4-methyl-1-((2R,5R)-5-methyl-5-vinyltetrahydrofuran-2-yl)pentan-1-ol 
• 1291070-00-2 tert-butyl(((S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methyl-4-((2S,3S)-3-((R)-3-methyl-3-((triethylsilyl)oxy)pent-4-en-1-yl)oxiran-2-yl)butan-2-yl)oxy)dimethylsilane 
• 1291069-96-9 (5S,12R,E)-5-(((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-14,14-diethyl-2,2,3,3,5,12-hexamethyl-12-vinyl-4,13-dioxa-3,14-disilahexadec-8-ene 
• 1291069-99-2 tert-butyl(((R)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbut-3-en-2-yl)oxy)dimethylsilane 
• 1291070-07-9 (2R,4R)-4-((tert-butyldimethylsilyl)oxy)-4-methylhex-5-ene-1,2-diol 
• 1291069-98-1 C₁₃H₂₆O₂Si 
• 1291069-97-0 (R,E)-triethyl((7-iodo-3-methylhepta-1,6-dien-3-yl)oxy)silane 
• 1291070-06-8 (R)-triethyl((3-methylhept-1-en-6-yn-3-yl)oxy)silane 
• 1291070-03-5 (S)-4-benzyl-3-((S,E)-6-hydroxy-2-((S)-hydroxy((1S,3R,5S)-5-methyl-1-((2R,5R)-5-methyl-5-vinyltetrahydrofuran-2-yl)-2,8-dioxabicyclo[3.2.1]octan-3-yl)methyl)-4-methylhex-4-enoyl)oxazolidin-2-one 
• 1291070-12-6 (S)-4-benzyl-3-((S,E)-6-((tert-butyldimethylsilyl)oxy)-2-((S)-hydroxy((1S,3R,5S)-5-methyl-1-((2R,5R)-5-methyl-5-vinyltetrahydrofuran-2-yl)-2,8-dioxabicyclo[3.2.1]octan-3-yl)methyl)-4-methylhex-4-enoyl)oxazolidin-2-one 
• 1035622-31-1 (S,E)-4-benzyl-3-(6-((tert-butyldimethylsilyl)oxy)-4-methylhex-4-enoyl)oxazolidin-2-one 
• 1291070-11-5 (E)-6-((tert-butyldimethylsilyl)oxy)-4-methylhex-4-enoic acid 

Relevant academic research and scientific papers

A convergent route to the CDEF-tetracycle of pectenotoxin-2

Chemical equations presented. A convergent synthesis of the CDEF-tetracyclic region of pectenotoxin-2 (PTX-2) is described. The synthetic pathway derives from a head-to-tail union of 2 equiv of linalool to establish a stereodefined DEF-tricyclic aldehyde.