1291098-83-3Relevant academic research and scientific papers
Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl]
Khan, Shabana,Sen, Sakya S.,Kratzert, Daniel,Tavcar, Gasper,Roesky, Herbert W.,Stalke, Dietmar
experimental part, p. 4283 - 4290 (2011/05/06)
Heteroleptic chlorosilylene (PhC(NtBu)2SiCl) (1) reacts with unsaturated organic compounds under oxidative addition. Reactions of 1 with cyclooctatetraene (COT) and a diimine afford [1+4]-cycloaddition products 3 and 6, respectively. In the cas
