1291100-06-5Relevant academic research and scientific papers
Enantiopure 1,4-diols and 1,4-aminoalcohols via stereoselective acyclic sulfoxide-sulfenate rearrangement
Fernandez De La Pradilla, Roberto,Colomer, Ignacio,Urena, Mercedes,Viso, Alma
supporting information; experimental part, p. 2468 - 2471 (2011/07/09)
Chemical equations presented. Treatment of acyclic α-hydroxy and α-tosylamino sulfinyl dienes with amines affords enantiopure 1,4-diol or 1,4-hydroxysulfonamide derivatives in good yields and diastereoselectivities. This one-pot procedure entails a conjugate addition that triggers a diastereoselective sulfoxide-sulfenate [2,3]-sigmatropic rearrangement.
