129111-03-1Relevant academic research and scientific papers
The effects of the carbonyl group in the cyclization of 1-hexenyl radicals
Serra,Da Silva Correa,Do Vale
, p. 9463 - 9488 (2007/10/02)
The radical chain cyclization of allyl ether derivatives promoted by tosyl halides and light is suppressed by the presence of one carbonyl group conjugated with the double bond (acrylic double bond).
RADICAL CHAIN CYCLIZATION OF ALLYLIC COMPOUNDS
Serra, A.C.,Silva Correa, C.M.M. da,Vieira, M.A.M.S.A.,Gomes, M.A.
, p. 3061 - 3070 (2007/10/02)
The light induced additions of tosyl iodide and tosyl bromide to some diallylic compounds and dienes are studied.Cyclization occurs in some cases but the yields are quite small.Results are discussed on the grounds of free radical cyclization.
