129115-57-7

Upstream product

• 19310-52-2 α-Cyano-α-<3-fluor-benzyliden>-essigsaeureaethylester 
• 41220-29-5 N-carbamoylmethylpyridinium chloride 
• 133828-86-1 pyridinium 1-carbamoylmethylide 
• 32727-94-9 1-(2-methoxy-2-oxoethyl)pyridin-1-ium bromide 
• 100908-62-1 (Z)-2-Cyano-3-(3-fluoro-phenyl)-acrylamide 
• 100908-62-1 2-cyano-3-(3-fluorophenyl)acrylamide 
• 105-56-6 ethyl 2-cyanoacetate 
• 456-48-4 3-Fluorobenzaldehyde 
• 107-91-5 cyanoacetic acid amide 
• 15725-42-5 ethyl 3-(3-fluorophenyl)-2-cyanoacrylate 

Relevant academic research and scientific papers

Regio- and stereoselective synthesis of tetrahydroindolysines, tetrahydropyridin-6-olates, and cyclopropanes from pyridinium ylides and unsaturated nitriles

The regio- and stereoselectivity of the reactions of pyridinium ylides with unsaturated nitriles are dependent on the electronic nature of the substituent in position 3 of the pyridine ring. The reaction of 1-carbamoylmethylide-3-cyanopyridinium with aryl

Stereoselective synthesis of trans-4,5-substituted 1,4,5,6-tetrahydropyridine-2-(olates)thiolates

trans-4,5-Substituted 1,4,5,6-tetrahydropyridine-2-(olates)thiolates are prepared either from pyridinium salts and cyanoacetic acid derivatives or from pyridinium salts, aromatic aldehydes and ethyl cyanoacetate or cyanoacetamide in the presence of a base

STEREOCHEMISTRY OF THE REACTION OF PYRIDINIUM YLIDES WITH α,β-UNSATURATED NITRILES

Regioselective and stereoselective methods were developed for the synthesis of 4-aryl-2-oxo-3-(1-pyridinio)-5-cyano-3,4-trans-1,2,3,4-tetrahydropyridin-6-olates from pyridinium ylides and α,β-unsaturated nitriles.The compounds were also obtained by the co