129145-42-2Relevant academic research and scientific papers
Efficient preparation of enantiomerically pure (E)-γ-hydroxy-α,β- unsaturated p-tolylsulfoxides using lipase-mediated acylations
Guerrero De La Rosa, Victor,Ordonez, Mario,Llera, Jose Manuel
, p. 2991 - 3001 (2007/10/03)
(E)-γ-Hydroxy-α,β-unsaturated p-tolylsulfoxides 1 have been efficiently resolved via irreversible enzymatic acylation with lipase PS (Pseudonomas cepacia) and vinyl acetate. (C) 2000 Elsevier Science Ltd.
A new system for catalytic enantioselective reduction of achiral ketones to chiral alcohols. Synthesis of chiral α-hydroxy acids
Corey,Bakshi
, p. 611 - 614 (2007/10/02)
The reduction of a variety of achiral ketones with catecholborane as stoichiometric reductant and 0.1 equiv of oxazaborolidine 2 as catalyst in toluene at -78°C proceeds in > 95% yield and with enantioselectivities in the range 30:1 to 9:1, depending on s
