129156-53-2Relevant academic research and scientific papers
Diastereoselective 1,4-addition of various nucleophiles to 5-trimethylsilyl-2-cyclohexenone: Synthesis of (+)-ramulosin
Asaoka, Morio,Sonoda, Shuzo,Fujii, Naoaki,Takei, Hisashi
, p. 1541 - 1552 (2007/10/02)
Base catalyzed reaction of active methylene compounds or oxygen catalyzed reaction of trialkylboranes via radical pathway with 5-trimethylsilyl-2-cyclohexenone (1) gave the corresponding products with modest to high (3:2- 20:1) diastereopurities. High dia
