129170-53-2

Basic information

• Product Name: (3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol
• Synonyms: (3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol
• CAS NO: 129170-53-2
• Molecular Weight: 554.961
• Mol File: 129170-53-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol(129170-53-2)
• EPA Substance Registry System: (3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol(129170-53-2)

Safety Data

• Hazardous Substances Data: 129170-53-2(Hazardous Substances Data)

Upstream product

• 91751-27-8 (3R,4R,5S)-6-(tert-butyldiphenylsiloxy)-4-hydroxy-3,5-dimethylhexan-1-ene 
• 106357-26-0 1-(tert-butyl-diphenyl-silanyloxy)-2(S),4(S)-dimethyl-hex-5-en-3(R)-ol 
• 95514-04-8 (R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 92817-88-4 (2S)-3-{[tert-butyl(diphenyl)silyl]oxy}-2-methylpropanal 
• 994-30-9 triethylsilyl chloride 
• 99687-40-8 (R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate 
• 1201668-13-4 (2R,3S,4S)-5-[(1,1-dimethylethyl)diphenylsilyloxy]-2,4-dimethyl-3-(triethylsilyloxy)-pentanal 
• 106357-33-9 (4S,5S)-2-[(2Z)-2-butenyl]-1,3,2-dioxaborolane-4,5-dicarboxylic acid bis(1-methylethyl) ester 
• 106568-13-2 (2S,3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-3-triethylsilanyloxy-pentanal 

Relevant articles and documents

Acyclic diastereoselective synthesis using tartrate ester modified crotylboronates. Double asymmetric reactions with α-methyl chiral aldehydes and synthesis of the C(19)-C(29) segment of rifamycin S

Double asymmetric reactions of the tartrate ester modified crotylboronates 1 and 2 and α-methyl chiral aldehydes are described. The reactions of the appropriate enantiomers of 1 and 2 with β-alkoxy-α-methylpropionaldehydes 11 provide adducts 12, 13, and 1