129200-01-7

Upstream product

• 129199-94-6 5-bromo-4-ethyl-6-methyl-1,2,3-triazine 
• 114078-85-2 5-Bromo-4-methyl-6-phenyl-[1,2,3]triazine 

Relevant academic research and scientific papers

The substitution of 5-halo-1,2,3-triazines with electrolytically generated superoxide

Electrolytically generated superoxide reacted with 5-halo-1,2,3-triazines 1 to afford 5-hydroxy-1,2,3-triazines 2. Reaction of 1 with hydroxide anion or potassium superoxide resulted in complicated mixture of products, therefore the reaction was specific for electrogenerated superoxide. The reaction mechanism was investigated with electrochemical methods, and it was revealed that one electron transfer from superoxide to 1 initialized the reaction.

Reaction of 5-halo-1,2,3-triazines with superoxide; synthesis of 5-hydroxy-1,2,3-triazlnes

5-Halo-1,2,3-triazines were allowed to react with electrolytically produced superoxide to give 5-hydroxy-1,2,3-triazines. Reaction with hydroxide anion gave ring opening products, therefore this substitution was specific for superoxide.