129200-97-1Relevant academic research and scientific papers
Catalytic Enantioselective Access to Dihydroquinoxalinones via Formal α-Halo Acyl Halide Synthon in One Pot
Crescenzi, Carlo,Lattanzi, Alessandra,Mancinelli, Michele,Mazzanti, Andrea,Meninno, Sara,Volpe, Chiara
supporting information, p. 23819 - 23826 (2021/10/04)
An enantioselective one-pot catalytic strategy to dihydroquinoxalinones, featuring novel 1-phenylsulfonyl-1-cyano enantioenriched epoxides as masked α-halo acyl halide synthons, followed by a domino ring-opening cyclization (DROC), is documented. A popula
Highly enantioselective conjugate additions of aldehydes to vinyl sulfones
Landa, Aitor,Maestro, Miguel,Masdeu, Carme,Puente, Angel,Vera, Silvia,Oiarbide, Mikel,Palomo, Claudio
supporting information; experimental part, p. 1562 - 1565 (2009/10/01)
The use of less basic chiral amine catalysts for highly enantioselective conjugate additions of aldehydes to vinyl sulfones was reported. The results show that the addition of aldehydes to α-cyano vinyl sulfones takes place at -40°C to give alcohols. The
Stereospecific synthesis of polysubstituted E-olefins by reaction of acyclic nitrones with free and platinum(II) coordinated organonitriles
Lasri, Jamal,Januario Charmier, M. Adilia,Haukka, Matti,Pombeiro, Armando J. L.
, p. 750 - 755 (2007/10/03)
(Chemical Equation Presented) Free nitriles NCCH2R (1a R = CO2Me, 1b R = SO2Ph, and 1c R = COPh) with an acidic α-methylene react with acyclic nitrones -O+N(Me)= C(H)R′ (2a R′ = 4-MeC6Hsub
Solid catalysts for the production of fine chemicals: The use of natural phosphate alone and doped base catalysts for the synthesis of unsaturated arylsulfones
Zahouily, Mohamed,Salah, Mohamed,Bahlaouane, Bouchaib,Rayadh, Ahmed,Houmam, Abdelaziz,Hamed, Emad A.,Sebti, Sa?d
, p. 1631 - 1635 (2007/10/03)
The inexpensive natural phosphate, both alone and doped with potassium fluoride, is a new basic catalyst for the synthesis of α,β- unsaturated arylsulfones. Activation by water and benzyltriethylammonium chloride has also been investigated. When using an
